WTe2 Crystal

SKU:
BLK-WTe2-FLX
Condition:
New
  • Large size WTe2 crystals - 2Dsemiconductors USA
  • Large size WTe2 crystals - 2Dsemiconductors USA
  • EDS spectrum of WTe2 crystals
  • XRD data from WTe2 crystals
  • Raman spectrum of WTe2 crystals
$590.00
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Description

Tungsten ditelluride (WTe₂) is a type-II Weyl semimetal known for several remarkable properties. Our WTe₂ crystals are grown at record low defect densities (~1×10¹⁰ cm⁻²) using sophisticated flux or conventional CVT technique (lower quality). Our crystals are designed in the last 15 years to ensure they exhibit premium electronic characteristics and regarded as the gold standard in sciences and engineering

Properties of WTe2 crystals from 2Dsemiconductors USA

Crystal size The current batch measures ~1.5cm
Material properties Type II Weyl semimetal
Crystal structure Orthorombic phase (P configuration)
Unit cell parameters a=0.351 nm, b=0.628, c=1.412 nm; α=β=γ=90°
Growth method [Default] Flux zone (no halide contamination) defect free
[Optional CVT]: Contains Br2, Cl2, TeCl4, and other halides
Purity 99.9999% confirmed

 

Growth method matters> Flux zone or CVT growth method? Contamination of halides and point defects in layered crystals are well known cause for their reduced electronic mobility, reduced anisotropic response, poor e-h recombination, low-PL emission, and lower optical absorption. Flux zone technique is a halide free technique used for synthesizing truly semiconductor grade vdW crystals. This method distinguishes itself from chemical vapor transport (CVT) technique in the following regard: CVT is a quick (~2 weeks) growth method but exhibits poor crystalline quality and the defect concentration reaches to 1E11 to 1E12 cm-2 range. In contrast, flux method takes long (~3 months) growth time, but ensures slow crystallization for perfect atomic structuring, and impurity free crystal growth with defect concentration as low as 1E9 - 1E10 cm-2. During check out just state which type of growth process is preferred. Unless otherwise stated, 2Dsemiconductors ships Flux zone crystals as a default choice. 

Highlights of our WTe2 crystals;
  • Crystals are grown by float zone technique to achieve defect free and environmentally stable WTe2 crystals. 
  • Our WTe2 crystals are stable in ambient conditions and no sealing or careful storage conditions needed.
  • Crystals do not contain any impurities like TeCl4 or Br2 coming from transport agents used in conventional CVT process. 
  • Each and every single crystal piece is characterized using EDAX, XRD, Raman, and hall measurements to unsure reproducible results with highest accuracy and confidence in crystals. 

XRD data collected from WTe2 crystals (sharpest XRD peaks in the commercial market)

wte2-xrd.png

Raman spectrum collected from WTe2 crystals (also sharpest and most defined Raman signal from commercial WTe2 crystals)

wte2-raman-spectrum.png

EDS spectrum collected from WTe2 crystals

wte2-eds-spectrum.png

 Partial List of Published Articles Using Our WTe2 Crystals (as of 2017)

L. A. Walsh et. al. "WTe2 thin films grown by beam-interrupted molecular beam epitaxy" 2Dmaterials, 4, 2 (2017)

P. Lu et.al. Origin of superconductivity in the Weyl semimetal WTe2 under pressure, Phys. Rev. B. 94, 224512 (2016)

M. Kim et. al. Determination of the thickness and orientation of few-layer tungsten ditelluride using polarized Raman spectroscopy, 2D Materials, Volume 3, Number 3

Y. Kim. et.al. Anomalous Raman scattering and lattice dynamics in mono- and few-layer WTe2, Nanoscale, 2016,8, 2309-2316

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Additional Information

Elements:
W,Te
Element:
Tungsten
Element:
Tellurium
Formula:
WTe2
Material class:
MX2
Material class:
Dichalcogen
Material class:
Quasi-1D
Properties:
Metal
Properties:
Superconductor
Properties:
Semimetal
Growth method:
CVT
Growth method:
Flux
Doping:
Undoped
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